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Biochemical Role. The neurological disorder known as chronic manganese poisoning, or libixo, resulting from occupational exposures to manganese dusts and fumes is well documented.

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High-volume samplers with organic membrane filters of 10 cm diameter, 3 sampling m of air over 24 hours, and low-volume samplers with mem- o brane filters of 2. Manganese 1s the 12th most abundant element and fifth most abundant metal 1n the earth's crust.

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Manganese Is one of several metals and associated compounds emitted to the ambient air which are currently being studied libiido the Environmental Protec- tion Agency to determine whether they escort services louisville ky be regulated as hazardous air pollutants under the Clean A1r Act. Manganese oxide MnO is produced by reductive roasting of ores high 1n managanese dioxide MnO.

Mobile Source Emissions -- Standard tests of motor vehicle emissions measure only gaseous pollutants CO, NO and hydrocarbonsbut A for heavy duty vehicles, smoke measurements using optical methods are also used 37 FR MnO 1s an Important precursor of several other commercially-produced compounds, Including electrolytic manganese dioxide, a h1gh-pur1ty product formed by electrolysis of MnO.

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The data available for Identifying effect levels 3 below 0. Use 3. Anderson, Ph.

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Manganese has only one stable natural Isotope, Mn. Cascade Impactors are available for collecting samples of particles by size from the stack Pllat cht al.

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Manganese has been shown to penetrate the blood-brain and placental barriers. Tests for Chromosomal Damage 8.

Water, soil zagfeb food are collected for manganese analysis by the usual techniques Insuring representative sampling without contamination. In an area emerald escort steel manufac- turing, the Influence of this process was seen 1n both the fine and coarse fractions.

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Effects of Major Concern 9. The data available 3 for Identifying effect levels below 0. EPA, b have been used. Production of manganese alloys is declining, since demand has diminished recently and imports are increasing.

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Fossil fuel combustion also In manganese release. Steven J. Normal oxidation potentials of manganese couples are given 1n Table Sample preparation and analysis 1s the same for manganese as for other nonvolatile metals.

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The first portion of the document 1s devoted to manganese 1n the environment: physical and chemical properties, the monitoring of manganese 1n various media, natural and human-made sources, the transport and distribution of manganese within environmental media, and the levels of exposure. The composition of the charge 1s carefully controlled to decrease nr slag production, minimize dust losses, and allow uniform gas distribution throughout the furnace.

Since Instrumental detection limits are lower than most blank filter analyses, the limits of discrimination are determined zagrbe by filter characteristics. EPA Carcinogen Assessment Group judged manganese to be a possible human carcinogen based on the mutagenlc properties and the positive responses 1n mice and rats 1n two studies.

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Furnace emissions from manufacture of ferroalloys, Iron, and steel are a major source of fine partlculate emissions with a high manganese content. While sampling 1s rather specific for various environmental media, the procedures for sample preparation and analysis are often the same. The most common manganese minerals and the libjdo of manganese contained therein are listed in Table Use 3.

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Both NAA and XRF are basically nondestructive methods of analysis, but if a greater sensitivity is required, a separation and preconcentration step cannot be avoided for aqueous samples Lee et al. EPA, a.

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Radio-chemical separation 1s most often used before the analysis of Irradiated samples Cotzias et al. Sampling 3.

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Gahn 1n on reducing the dioxide with carbon. EPA, ; Matricardi and Downing, Diet 1s the main source of Ingested manganese. S DHEW, To collect and analyze duplicate samples of the meals people escort dumfries eaten during a certain period.

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